In plesk 10 you will not an option or Icon to add a domain administrator account for any of your domain.
And as you wish to add a domain administrator account you will need to add a user and then assign proper permissions to that particular user. You can follow the bellow given steps:
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Login to control panel.
Click on Subscriptions.
Click on control panel. (Check in front of the domain name for which you want to add domain administrotr user)
Click on users tab.
In tab "Users" you can create/configure user accounts and user roles as you want
Create accounts with necessary privileges.
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Carol.P
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