It happens because the php 5.3 is not fully compatible with Plesk 8.6.
In a work around you can try to edit the following files.
Quote:
/usr/share/psa-horde/imp/lib/IMAP/Client.php line 576
modify function namespace($additional = array())
with function plnamespace($additional = array())
/usr/share/psa-horde/imp/lib/Session.php line 295
modify $_SESSION['imp']['namespace'] = $imapclient->namespace($user_namespace);
with $_SESSION['imp']['namespace'] = $imapclient->plnamespace($user_namespace);
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Reload the webmail page and logout/login again.